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Penetration of chlorides

Chlorides can reach into the concrete from the use of de-icing salts, from seawater or from the air (e. g. sea-air, PVC-Fire). In the presence of humidity and oxygen, corrosion can occur due to a critical free chloride content at the surface of the reinforcement. As in the case of carbonation, the quality of the concrete cover is decisive for the avoidance of corrosion.

Figure 1: Influence of ggbs on the diffusion coefficient for chloride [Bro83]
Figure 2: Influence of fly ash (FA) on the migration coefficient for chloride [Wie00]

The use of cements containing ggbs or fly ash can result in an significant increase in the resistance against chloride penetration (Figures 1 and 2). This can be attributed to the reduction of capillary pores and the higher amount of finer pores in the cement paste when using these cements.

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